Jing et al. enhanced the electrochemical energy storage capability of lithium titanate over a wider voltage range (0.01–3 V vs. Li + /Li) (see Fig. 9 (A)) by attaching carbon particles to the surface.
The co-doping approach of Li-site and O-site was proposed as an innovative modification concept to enhance the electrochemical performance of lithium titanate. The second approach involves the partial substitution of cheap Na for Li might lower the cost of producing lithium titanate.
The experimental results indicate that the modified lithium titanate exhibited significant improvements in specific capacity, rate, and cycle stability, with values of 305.7 mAh g−1 at 0.1 A g −1, 157 mAh g −1 at 5 A g −1, and 245.3 mAh g −1 at 0.1 A g −1 after 800 cycles.
These findings encourage the utilization of niobium-doped lithium titanate (Li 4 Ti 4.95 Nb 0.05 O 12) as a high-rate anode in lithium-ion batteries. Sreejith et al. generated ex-situ carbon-coated lithium titanate doped with tin (Sn4+) through conventional solid-state synthesis.
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